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Isothermal compressibility and anisotropic structural response of As2O5 under pressure Export

Solid State Communications (30 October 2009)

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The isothermal compressibility of As2O5 has been studied up to a pressure of 19.5 GPa. High resolution X-ray powder diffraction and a membrane driven diamond anvil cell were used to determine the bulk moduli and their pressure derivatives according to various Equations of States and to investigate a potential transformation to a high pressure polymorph. A mechanism which inhibits such a phase transformation up to the maximum applied pressure was revealed.


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