Superparamagnetic High-Magnetization Microspheres with an Fe3O4@SiO2 Core and Perpendicularly Aligned Mesoporous SiO2 Shell for Removal of Microcystins

Superparamagnetic microspheres with an Fe3O4@SiO2 core and a perpendicularly aligned mesoporous SiO2 shell were synthesized through a surfactant-templating sol?gel approach. The microspheres possess high magnetization (53.3 emu/g), high surface area (365 m2/g), large pore volume (0.29 cm3/g), and uniform mesopore (2.3 nm). By using the unique core?shell microspheres with accessible large pores and excellent magnetic property, a fast removal of microcystins with high efficiency (>95%) can be achieved.