A 2D model for tube orientation and tube squeezing in fast flows of polymer melts Export

@article{citeulike:889843, abstract = {Motivated by recent data of Hassager and coworkers [A. Bach, K. Almdal, H.K. Rasmussen, O. Hassager, Elongational viscosity of narrow molar mass distribution polystyrene, Macromolecules, 36 (2003) 5174–5179], we develop a new tube model describing the non-linear behaviour of entangled monodisperse linear polymers. Within the context of well established tube theories, the model accounts for the effect of flow on tube diameter, thus somehow picking up a long standing suggestion by Wagner and Schaeffer [M.H. Wagner, J. Schaeffer, Non-linear strain measures for general biaxial extension of polymer melts, J. Rheol., 32 (1992) 1–26] among others. Since tubes with a deformation dependent cross section are rather difficult to deal with, we here limit model development to an artificial two-dimensional situation. The simple 2D model has the advantage of illustrating the new physical assumptions more transparently, and it already proves to correctly predict most qualitative features typically shown by shear and elongational data in the non-linear range.}, author = {Marrucci, G. and Ianniruberto, G.}, booktitle = {40th International Symposium on Macromolecules}, citeulike-article-id = {889843}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/j.jnnfm.2005.01.007}, citeulike-linkout-1 = {http://linkinghub.elsevier.com/retrieve/pii/S0377025705000868}, citeulike-linkout-2 = {http://www.sciencedirect.com/science/article/B6TGV-4G4XBV2-3/2/fe48dcde458f312820eebc8aca7d8b5d}, day = {01}, doi = {10.1016/j.jnnfm.2005.01.007}, issn = {03770257}, journal = {Journal of Non-Newtonian Fluid Mechanics}, keywords = {2d, bach, explain, marrucci, model, to}, month = {June}, number = {1}, pages = {42--49}, posted-at = {2009-11-04 10:49:16}, priority = {2}, title = {A 2D model for tube orientation and tube squeezing in fast flows of polymer melts}, url = {http://dx.doi.org/10.1016/j.jnnfm.2005.01.007}, volume = {128}, year = {2005} }

TY - JOUR ID - citeulike:889843 L3 - citeulike-article-id:889843 N2 - Motivated by recent data of Hassager and coworkers [A. Bach, K. Almdal, H.K. Rasmussen, O. Hassager, Elongational viscosity of narrow molar mass distribution polystyrene, Macromolecules, 36 (2003) 5174–5179], we develop a new tube model describing the non-linear behaviour of entangled monodisperse linear polymers. Within the context of well established tube theories, the model accounts for the effect of flow on tube diameter, thus somehow picking up a long standing suggestion by Wagner and Schaeffer [M.H. Wagner, J. Schaeffer, Non-linear strain measures for general biaxial extension of polymer melts, J. Rheol., 32 (1992) 1–26] among others. Since tubes with a deformation dependent cross section are rather difficult to deal with, we here limit model development to an artificial two-dimensional situation. The simple 2D model has the advantage of illustrating the new physical assumptions more transparently, and it already proves to correctly predict most qualitative features typically shown by shear and elongational data in the non-linear range. IS - 1 JF - Journal of Non-Newtonian Fluid Mechanics SN - 03770257 EP - 49 TI - A 2D model for tube orientation and tube squeezing in fast flows of polymer melts VL - 128 T2 - 40th International Symposium on Macromolecules SP - 42 KW - 2d KW - bach KW - explain KW - marrucci KW - model KW - to AU - Marrucci, G AU - Ianniruberto, G PY - 2005/06/01/ UR - http://dx.doi.org/10.1016/j.jnnfm.2005.01.007 ER -