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Effect of BeO Addition on Sintering of Transparent Y2O3by: Gyozo Toda, Iwao Matsuyama
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AbstractThe effects of BeO addition (0~2 wt%) on the pressureless sintering process and the transparency of yttria were studied. The addition of BeO (0.1~0.5 wt%) promoted the sintering of Y2O3 to decrease markedly the residual pores in sintered bodies above 2100°C. The transparency of sintered Y<sub>2</sub>O<sub>3</sub> was independent of compacting pressure (i~10 t/cm<sup>2</sup>). BeO vaporized with the increase of sintering temperature and more than half of the initial contents of BeO decreased above 1800°C. The transmittance (thickness 1.0 mm, wave length 300~700 nm) of the 0.1 wt% BeO-Y<sub>2</sub>O<sub>3</sub> sintered at 2150~2250°C for 50~300 min. in H<sub>2</sub> was 80%. Tit was suggested that the liquid phase formation of Y<sub>2</sub>O<sub>3</sub>-BeO system and the vaporization of BeO contributed to the fabricating of the transparent Y<sub>2</sub>O<sub>3</sub>.
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