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Improvements in Atmosphere Sintering of Transparent PLZT Ceramics Export

Journal of the American Ceramic Society, Vol. 56, No. 9. (1973), pp. 479-480.

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An improved atmosphere sintering process was developed for fabricating large transparent PLZT plates for electrooptic applications. Cold-pressed 9/85/35 PLZT slugs were sintered in O2 in Pt crucibles for ~45 min at 1180oC and were then heat-treated in air for 60 h at 1200oC in Al2O3 crucibles containing PbZrO3 atmosphere powder. Transparent plates as large as 8.4 cm in diameter and I cm thick were thus fabricated. A mechanism is proposed which qualitatively accounts for the success of this process.


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