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Method for sintering high density yttria-gadolinia ceramic scintillators Export

United States Patent, Vol. 4473513 (25 September 1984)

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dy gadolinia nb oxalate patent pr scintillator tb transparent_ceramic wet yb yttria

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A method for preparing high density yttria-gadolinia ceramic scintillators includes cold-pressing a multicomponent powder to form powder compacts and then sintering the compacts to form transparent-to-translucent ceramic scintillator bodies. The powder compacts are formed by either die pressing or die pressing followed by isostatic pressing to further increase green density. The powder compacts are sintered in vacuum or a reducing atmosphere at a temperature of between 1800.degree. C. and 2100.degree. C. The preferred heating sequence includes a holding period at a temperature lower than the final sintering temperature. The finished scintillator includes Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and one or more of Eu.sub.2 O.sub.3, Nd.sub.2 O.sub.3, Yb.sub.2 O.sub.3, Pr.sub.2 O.sub.3, Dy.sub.2 O.sub.3, and Tb.sub.2 O.sub.3 rare earth activator oxides. The finished scintillator may also include at least one of SrO and CaO as afterglow reducers.


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