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J. Mater. Chem., Vol. 20, No. 16. (2010), pp. 3287-3294, doi:10.1039/b923752f Key: citeulike:12034467
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A new C60-end capped poly(3-hexylthiophene) (P3HT-C60) was synthesized via a simple three-step process, and used as a compatibilizer for P3HT/PCBM composite for the purpose of controlling the morphology of P3HT/PCBM composite film, and thus improving the long-term thermal stability of solar cell performance. When a small amount of P3HT-C60 was added to P3HT/PCBM, the bicontinuous and nanometre-scale film morphology was developed and preserved for 2 h of annealing at 150 [degree]C. Furthermore, the addition of P3HT-C60 as a compatibilizer suppressed large-scale phase separation of P3HT/PCBM composite even after prolonged annealing time (8 days), and as a result, the P3HT/PCBM/P3HT-C60 bulk heterojunction solar cells exhibited the excellent long-term thermal stability of device performance.
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