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On the Blue Complexes Formed in Acidic Solutions of Hexaammineruthenium(II) Export

Can. J. Chem., Vol. 49, No. 22. (1971), pp. 3739-3743.

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absorption ruhex solution

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Abstract: The blue complex formed by reaction of hexaammineruthenium(II) dichloride and hydrochloric acid bas been characterized by analytical, spectroscopic, electrochemical, and chemical methods as a chlorobridged ruthenium(II)–ruthenium(III) dimer, [Ru2(NH3)6Cl4H2O]Cl. With hydrobromic acid the analogous complex [Ru2(NH3)6Br4H2O]Br is formed. Reactions of the complexes with ammonia and hydrohalic acids are reported. Résumé : Le complexe bleu, obtenu en faisant réagir le dichlorure d'hexaammineruthénium(II) avec l'acide chlorhydrique a été caractérisé par des méthodes analytiques, spectroscopiques, électrochimiques et chimiques; il s'agit d'un dimère ruthénium(II)–ruthénium(III) avec un pont chloro, [Ru2(NH3)6Cl4H2O]Cl. Avec l'acide bromhydrique, le complexe correspondant, [Ru2(NH3)6Br4H2O]Br, est obtenu. Les réactions de ces complexes avec l'ammoniaque et les acides halogénhydriques sont rapportées.


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