The role of amine structure on catalytic activity for silylation reactions with Cab-O-Sil Export

@article{citeulike:1838008, abstract = {Reactions between trimethoxymethylsilane and Cab-O-Sil in toluene were conducted in the presence of ethylamine, diethylamine, triethylamine, ammonia, and pyridine. Amines with exchangeable protons were found to catalyze the reaction to a significantly larger extent than those without such protons. However, even pyridine had a catalytic effect. Two mechanisms are proposed to explain the results.}, author = {Blitz, J. P. and Shreedhara and Leyden, D. E.}, citeulike-article-id = {1838008}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/0021-9797(88)90137-3}, citeulike-linkout-1 = {http://www.sciencedirect.com/science/article/B6WHR-4CX6RH9-8Y/2/5e2596ee785139a53f55b6c92c1aa8ae}, doi = {10.1016/0021-9797(88)90137-3}, journal = {Journal of Colloid and Interface Science}, keywords = {amines}, month = {December}, number = {2}, pages = {387--392}, posted-at = {2007-10-30 00:08:06}, priority = {2}, title = {The role of amine structure on catalytic activity for silylation reactions with Cab-O-Sil}, url = {http://dx.doi.org/10.1016/0021-9797(88)90137-3}, volume = {126}, year = {1988} }

TY - JOUR ID - citeulike:1838008 L3 - citeulike-article-id:1838008 N2 - Reactions between trimethoxymethylsilane and Cab-O-Sil in toluene were conducted in the presence of ethylamine, diethylamine, triethylamine, ammonia, and pyridine. Amines with exchangeable protons were found to catalyze the reaction to a significantly larger extent than those without such protons. However, even pyridine had a catalytic effect. Two mechanisms are proposed to explain the results. IS - 2 JF - Journal of Colloid and Interface Science EP - 392 TI - The role of amine structure on catalytic activity for silylation reactions with Cab-O-Sil VL - 126 SP - 387 KW - amines AU - Blitz, JP AU - Shreedhara AU - Leyden, DE PY - 1988/12// UR - http://dx.doi.org/10.1016/0021-9797(88)90137-3 ER -