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Structural investigations and luminescence of In<SUB><FONT SIZE='-1'>2</FONT></SUB>Ge<SUB><FONT SIZE='-1'>2</FONT></SUB>O<SUB><FONT SIZE='-1'>7</FONT></SUB> and In<SUB><FONT SIZE='-1'>2</FONT></SUB>Si<SUB><FONT SIZE='-1'>2</FONT></SUB>O<SUB><FONT SIZE='-1'>7</FONT></SUB> Export

Zeitschrift für anorganische und allgemeine Chemie, Vol. 620, No. 11. (1994), pp. 1965-1970.

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absorbance germanate germanium indium oxide pl xrd

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The crystal structures of the ordinary pressure forms of indium digermanate In2Ge2O7 and disilicate In2Si2O7 have been studied from X-ray powder diffraction data by Rietveld refinement. They are closely related to that of the thortveitite which crystallizes in the monoclinic system with the space group C2/m and Z = 2. They show luminescence properties below 160 K and 200 K respectively. The luminescence is discussed in terms of crystal structure and compared to that of some other luminescent indium oxides.


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