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The Effects of Organic Compounds on Inhibition of Hydrogen Permeation Through a Mild Steel Membrane Export

Journal of the Electrochemical Society, Vol. 144, No. 7. (1997), pp. 2313-2317.

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compounds electrochemical fe hydrogen organic permeation steel

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The effectiveness of 5-(4-pyridyl)-2,7-nonadiene, and 1 phenyl-2-propyn-ol (PP) on inhibition of the hydrogen evolution reaction on a 1010 steel membrane and on the degree of hydrogen ingress into the membrane was determined. Hydrogen evolution rates and permeation currents were monitored as a function of time at different applied potentials. In the presence of 0.5 g/liter PP in the electrolyte, the hydrogen discharge and permeation current density were inhibited by 98 and 95%, respectively.


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