Diffusion of hydrogen through metallic multilayers Export

@article{citeulike:1538195, abstract = {Electrochemical measurements of hydrogen permeation through Pd/Nb multilayers on Pd substrates are described. Pronounced retardation of permeation is observed for small hydrogen contents. To clarify whether this effect is due to special interface hydrogen states; the permeation is modeled based on the bulk properties of the pure metals. The model is sufficient to explain the retardation; which stems from the different free energies of hydrogen dissolution in both metals. At higher hydrogen contents a more complicated permeation behavior is observed; which is not yet well understood.}, author = {Schmitz, G. and Kesten, Ph and Kirchheim, R. and Yang, Q. M.}, citeulike-article-id = {1538195}, citeulike-linkout-0 = {http://dx.doi.org/10.1103/PhysRevB.58.7333}, citeulike-linkout-1 = {http://link.aps.org/abstract/PRB/v58/i11/p7333_1}, citeulike-linkout-2 = {http://link.aps.org/pdf/PRB/v58/i11/p7333_1}, day = {15}, doi = {10.1103/PhysRevB.58.7333}, journal = {Physical Review B}, keywords = {diffusion, electrochemical, hydrogen, layer, multi, permeation}, number = {11}, pages = {7333+}, posted-at = {2007-08-06 15:05:38}, priority = {2}, publisher = {American Physical Society}, title = {Diffusion of hydrogen through metallic multilayers}, url = {http://dx.doi.org/10.1103/PhysRevB.58.7333}, volume = {58}, year = {1998} }

TY - JOUR ID - citeulike:1538195 L3 - citeulike-article-id:1538195 N2 - Electrochemical measurements of hydrogen permeation through Pd/Nb multilayers on Pd substrates are described. Pronounced retardation of permeation is observed for small hydrogen contents. To clarify whether this effect is due to special interface hydrogen states; the permeation is modeled based on the bulk properties of the pure metals. The model is sufficient to explain the retardation; which stems from the different free energies of hydrogen dissolution in both metals. At higher hydrogen contents a more complicated permeation behavior is observed; which is not yet well understood. IS - 11 JF - Physical Review B TI - Diffusion of hydrogen through metallic multilayers PB - American Physical Society VL - 58 SP - 7333 KW - diffusion KW - electrochemical KW - hydrogen KW - layer KW - multi KW - permeation AU - Schmitz, G AU - Kesten, Ph AU - Kirchheim, R AU - Yang, QM PY - 1998//15/ UR - http://dx.doi.org/10.1103/PhysRevB.58.7333 ER -