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Photochemical Synthesis of Monodisperse Size-Controlled Silver Decahedral Nanoparticles and Their Remarkable Optical Properties

by: Brendan Pietrobon, Vladimir Kitaev
Chem. Mater. In Chemistry of Materials, Vol. 20, No. 16. (19 July 2008), pp. 5186-5190, doi:10.1021/cm800926u  Key: citeulike:12034962

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Abstract

Silver decahedral nanoparticles have been synthesized photochemically with excellent shape yields and monodisperse sizes, which could be varied by regrowth from ca. 35 to 120 nm. The decahedra exhibit remarkable optical properties: striking bicolored appearance, narrow tunable plasmon peaks and excellent enhancement of Raman scattering compared to other silver nanoshapes.


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