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New J. Chem., Vol. 36, No. 3. (2012), pp. 768-773, doi:10.1039/c2nj20943h Key: citeulike:11396653
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Original aza-bodipy dyes functionalised by thiophene moieties in 3,5 or 1,7 positions were prepared and characterised by X-ray crystallography. The 3,5 substituted compound 3 exhibits promising photophysical properties red-shifted in the NIR spectral range. Furthermore, the presence of bromide atoms has allowed [small pi]-conjugated skeleton extension via Sonogashira cross-coupling.
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