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A Fluorescence-Enhanced Chemodosimeter for Fe3+ Based on Hydrolysis of Bis(coumarinyl) Schiff Base

by: Weiying Lin, Lin Yuan, Jianbo Feng, Xiaowei Cao
Eur. J. Org. Chem., Vol. 2008, No. 16. (2008), pp. 2689-2692, doi:10.1002/ejoc.200800077  Key: citeulike:11450772

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Abstract

Bis(coumarinyl) Schiff base 1 was designed and synthesized as a fluorescence turn-on chemodosimeter for Fe3+. The chemodosimeter was readily synthesized in four steps from 2,4-dihydroxybenzaldehyde. The addition of Fe3+ to chemodosimeter 1 induced about a 140-fold enhancement influorescence. Furthermore, chemodosimeter 1 was also highly selective to Fe3+ over other metal ions, and most of the related metals ions exhibited negligible detection interference.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)


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