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Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework

by: Brandon R. Groves, Sarah M. Crawford, Travis Lundrigan, Cherif F. Matta, Shahin Sowlati-Hashjin, Alison Thompson
Chem. Commun., Vol. 49, No. 8. (2013), pp. 816-818, doi:10.1039/c2cc37480c  Key: citeulike:12005045

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Abstract

An improved and scalable synthesis of the unsubstituted 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene framework facilitates access to the previously unreported parent dipyrrin HCl salt, as well as 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene.


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