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Large Stokes Shift Induced by Intramolcular Charge Transfer in N,O-Chelated Naphthyridine–BF2 Complexes

by: Yun-Ying Wu, Yong Chen, Gao-Zhang Gou, Wei-Hua Mu, Xiao-Jun Lv, Mei-Ling Du, Wen-Fu Fu
Org. Lett. In Organic Letters, Vol. 14, No. 20. (10 October 2012), pp. 5226-5229, doi:10.1021/ol302347m  Key: citeulike:12005056

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Abstract

Novel N,O-chelated naphthyridine?BF2 complexes with push?pull structures have been synthesized and characterized. Spectral investigations on these complexes reveal that photoinduced intramolecular charge transfer occurs and results in a large Stokes shift, which is further supported by density functional theory based theoretical calculations.


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