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On the relationship between emission color and Ce3+ concentration in garnet phosphors Export

Optical Materials, Vol. 29, No. 12. (August 2007), pp. 1647-1652.

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emission energytransfer excitation luminescence

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It is known that the emission color of Ce 3+ doped garnets is strongly redshifted at higher Ce 3+ concentrations. In this report, we study the cause of this redshift in Lu 3 Al 5 O 12 :Ce 3+ (LuAG:Ce) phosphors. These changes in emission color with Ce 3+ concentration are mainly attributed to a combination of inhomogenous broadening for Ce 3+ in LuAG and energy transfer from high energy Ce 3+ ions to low energy Ce 3+ ions. Evidence for inhomogenous broadening and energy transfer is given through time resolved measurements. Potential reasons for inhomogenous broadening of Ce 3+ in these phosphors are also discussed.


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