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Dual Process Dielectric Formation for Decoupling Capacitors on Flexible SubstratesComponents and Packaging Technologies, IEEE Transactions on In Components and Packaging Technologies, IEEE Transactions on, Vol. 30, No. 4. (2007), pp. 579-584.
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AbstractLarge area, high density integrated capacitors within printed wiring boards can provide a substantial decoupling capacitance with very low parasitic inductance. Tantalum pentoxide (Ta<sub>2</sub>O<sub>5</sub>) is an excellent dielectric for this application due to the relatively high dielectric constant (~ 22-24), however the difficulty of fabricating large, defect-free capacitors has thus far prevented the realization of practical applications. This work demonstrates high performance capacitors with Ta<sub>2</sub>O<sub>5</sub> dielectric developed with a two step oxidation scheme consisting of reactive sputtering followed by anodization. Thin films of Ta<sub>2</sub>O<sub>5</sub> were deposited by reactive sputtering on silicon and also on Upilex<sup>reg</sup> covered glass wafers using dc magnetron sputtering with a gas flow ratio of 10/90 O<sub>2</sub>/Ar. In the two-step oxidation scheme, anodization is performed after reactively sputtering tantalum oxide films to obtain a densifled oxide structure. The electrical and physical properties of these two step sputtered/ anodized tantalum oxide films are shown to be superior to those of tantalum oxide films prepared by either anodization or sputtering alone. This work has shown that Ta<sub>2</sub>O<sub>5</sub> is a potential dielectric for integrated capacitors that could be used in advanced packaging applications.
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