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Short-~and long-range correlated motion observed in colloidal glasses and liquids

by: John, DA Weitz
Journal of Physics: Condensed Matter, Vol. 19, No. 20. (2007)


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We use a confocal microscope to examine the motion of individual particles in a dense colloidal suspension. Close to the glass transition, particle motion is strongly spatially correlated. The correlations decay exponentially with particle separation, yielding a dynamic length scale of O(2-3s) (in terms of particle diameter s). This length scale grows modestly as the glass transition is approached. Further, the correlated motion exhibits a strong spatial dependence on the pair correlation function g(r). Motion within glassy samples is weakly correlated, but with a larger spatial scale for this correlation.


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