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In Situ Observation of Fringing-Field-Induced Phase Separation in a Liquid-Crystal--Monomer Mixture

by: Hongwen Ren, Shin T Wu, Yi H Lin
Physical Review Letters, Vol. 100, No. 11. (2008)


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Fringing-field-induced phase separation dynamics in liquid-crystal–(LC-)monomer mixtures is investigated via a microscope. At a low LC concentration, the fringing field converts the randomly dispersed LC droplets to an ordered droplet array, while at a high LC concentration the fringing field converts the amorphous LC-monomer system to a composite film. Because the LC and monomer are immiscible, the converted morphologies are stable even after the voltage is removed. Using the fringing field-induced phase separation, it is possible to prepare different polymer-dispersed LC morphologies.


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