A quantum state is non-classical when its representation in phase space cannot be interpreted as a probability distribution. In this Letter, we present a map that can detect all non-classical states and translate it into its dual formalism, non-classicality witnesses. The map enables us to show that non-positive (i.e. non-physical) Hermitian operators may correspond to positive quasi-probability distributions in any $s$-ordered representation except only the normally ordered one. This exploits the geometrical structure of positive operators over positive $s$-ordered quasi-probability distributions, based on which, for multi-mode states we geometrically identify the fraction of the non-classicality depth that corresponds to quantum correlations of states: the non-classicality depth of entanglement.