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Precious Metals and Provenance Enquiries using LA-ICP-MS |
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AbstractWhile the manufacture technology of archaeological gold and silver objects can often be explained by using classical analytical techniques, the origin of these precious metals remains difficult to determine. In most cases, several trace elements and/or lead isotope ratios must be measured in order to find the object to mine. Very few results are known in this kind of research: lead isotope ratios are often insufficient and trace elements are difficult to determine non-destructively at very low concentrations. Reaching detection limits below the ppm level and determining a wide range of elements, ICP-MS, either in liquid or laser ablation configuration, finds one of its most interesting applications here. Our aim is to present the possibilities and limitations of this technique for the pre-selection of lead isotope ratios groups in silver and for the characterization of several monetary gold ore sources.
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