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We report on high-resolution electron-energy-loss measurements of surface-plasmon losses on Ag(001) performed for crystal temperatures T in the range 100–400 K. Both the surface-plasmon frequency and linewidth are found to depend on T. The surface-plasmon frequency decreases with increasing T, nearly independently of wave vector; the linewidth increases by 7×10-5 eV/K. The shift in energy is explained by the thermal expansion of the crystal, while the linewidth is influenced by the surface-plasmon–phonon interaction.
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