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Oxidation mechanism of LaTiO_3.5 thin films Export

Physical Review B, Vol. 63, No. 20. (12 April 2001), 205401.

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film latio3

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LaTiO 3.5 is a layered compound made up of four LaTiO 3 units:âtwo regular perovskite units stacked between two distorted units that share an additional oxygen layer. In a single-crystalline thin film the (100) plane can be aligned parallel to the substrate surface; i.e.; the additional oxygen layers are inserted parallel to the substrate surface. A detailed structural characterization reveals planar defects originating from substrate surface steps. These results; in combination with the in situ reflection high-energy electron-diffraction observations; suggest an oxidation mechanism using such antiphase boundaries as oxidation paths.


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