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Epitaxial growth and electronic structure of LaTiO[sub x] films Export

Applied Physics Letters, Vol. 80, No. 21. (2002), pp. 3922-3924.

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film latio3 sto

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LaTiOx films have been grown on (001) perovskite oxide substrates by pulsed-laser deposition. Both single-phase perovskite LaTiO3 and layered La2Ti2O7 films could be stabilized by varying the oxygen partial pressure and substrate temperature during growth. We have obtained a crystallographic and electronic phase diagram for LaTiOx films, demonstrating the ability to vary the titanium valence from 3+ to 4+ in thermodynamically unfavorable growth conditions by utilizing interface energies. ©2002 American Institute of Physics.


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