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Intracavity laser absorption spectroscopy of N2O with a vertical external cavity surface emitting laser Export

Chemical Physics Letters, Vol. 351, No. 1-2. (4 January 2002), pp. 18-26.

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diode-laser icas intra-cavity n2o spectroscopy

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The Intracavity Laser Absorption Spectrum (ICLAS) of nitrous oxide, 12N216O, has been recorded between 9560 and 9980 cm−1 with a Vertical External Cavity Surface Emitting Laser (VECSEL). Thirteen bands were observed, 11 of which are new. The rovibrational analysis has revealed the occurrence of a number of local perturbations due to anharmonic or Coriolis couplings, which could be analysed on the basis of the polyad model of effective Hamiltonian.


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