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Intramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and Dienes Export

Organic Letters, Vol. 7, No. 18. (1 September 2005), pp. 3917-3920.

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42 benzyne cycloaddition danheiser enyne mit

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PMID: 16119931 Benzynes generated by the reaction of o-(trimethylsilyl)aryl triflates with TBAT participate in intramolecular [4 + 2] cycloadditions with conjugated enynes, arenynes, and dienes to furnish highly condensed polycyclic aromatic compounds.


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