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Excitation spectra of CdRg (Rg=He, Ne, Xe) complexes recorded at the D1Σ0+←X1Σ0+ transition: From the heaviest CdXe to the lightest CdHe Export

Chemical Physics Letters (12 February 2009)

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Laser-induced fluorescence excitation spectra of CdRg (Rg = He, Ne, Xe) complexes were recorded at the inlMMLBox bound ← bound and free ← bound transitions. In case of CdXe, analysis of the recorded profiles resulted in determination of the inlMMLBox -state potential energy curve and ground-state dissociation energy. In case of CdHe and CdNe, analysis of the free ← bound profiles provided a repulsive part of the inlMMLBox -state potential. Valence ab initio calculations of the ground- and excited-state potentials and electronic transition dipole moments of the studied transition were performed taking scalar-relativistic and spin-orbit effects into account. The results were supplemented with those for CdAr and CdKr of our earlier study.


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