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Infrared and Raman study of the optical phonons in Bi4Ge3O12 single crystal Export

Solid State Communications, Vol. 20, No. 5. (November 1976), pp. 461-465.

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bgo phonons raman

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Infrared reflection and polarized Raman scattering spectra of cubic Td6 Bi4Ge3O12 single crystals were recorded, allowing the classification of the observed phonon modes into the different allowed symmetry. There is a good agreement with group theoretical predictions, since 25 phonon modes are localized, among the expected 27 ones. An assignment in terms of the GeO4 "tetrahedra" vibrations is tentatively given and discussed.


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