The first high oxidation state manganese-calcium cluster: relevance to the water oxidizing complex of photosynthesis.

@article{citeulike:277977, abstract = {Synthetic entry has been achieved into high oxidation state Mn-Ca cluster chemistry with the preparation of [Mn(13)Ca(2)O(10)(OH)(2)(OMe)(2)(O(2)CPh)(18)(H(2)O)(4)]; the structure contains [Mn(4)CaO(4)] sub-units similar to that found in the photosynthetic water oxidizing complex.}, address = {Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA.}, author = {Mishra, A. and Wernsdorfer, W. and Abboud, K. A. and Christou, G.}, citeulike-article-id = {277977}, doi = {10.1039/b413680b}, issn = {1359-7345}, journal = {Chem Commun (Camb)}, keywords = {mn, oec}, month = {January}, number = {1}, pages = {54--56}, posted-at = {2005-08-10 12:23:38}, priority = {2}, title = {The first high oxidation state manganese-calcium cluster: relevance to the water oxidizing complex of photosynthesis.}, url = {http://dx.doi.org/10.1039/b413680b}, year = {2005} }

TY - JOUR ID - citeulike:277977 L3 - citeulike-article-id:277977 N2 - Synthetic entry has been achieved into high oxidation state Mn-Ca cluster chemistry with the preparation of [Mn(13)Ca(2)O(10)(OH)(2)(OMe)(2)(O(2)CPh)(18)(H(2)O)(4)]; the structure contains [Mn(4)CaO(4)] sub-units similar to that found in the photosynthetic water oxidizing complex. IS - 1 JF - Chem Commun (Camb) SN - 1359-7345 AD - Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA. EP - 56 TI - The first high oxidation state manganese-calcium cluster: relevance to the water oxidizing complex of photosynthesis. SP - 54 KW - mn KW - oec AU - Mishra, A AU - Wernsdorfer, W AU - Abboud, KA AU - Christou, G PY - 2005/01/07/ UR - http://dx.doi.org/10.1039/b413680b ER -