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Slow dynamics in cylindrically confined colloidal suspensions

by: Nabiha Saklayen, Gary L. Hunter, Kazem V. Edmond, Eric R. Weeks

edited by: Michio Tokuyama, Irwin Oppenheim

AIP Conference Proceedings, Vol. 1518, No. 1. (2013), pp. 328-335, doi:10.1063/1.4794593  Key: citeulike:12079625

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Abstract

We study bidisperse colloidal suspensions confined within glass microcapillary tubes to model the glass transition in confined cylindrical geometries. We use high speed three-dimensional confocal microscopy to observe particle motions for a wide range of volume fractions and tube radii. Holding volume fraction constant, we find that particles move slower in thinner tubes. The tube walls induce a gradient in particle mobility: particles move substantially slower near the walls. This suggests that the confinement-induced glassiness may be due to an interfacial effect.


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