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Reentrant Surface Melting of Colloidal Hard Spheres Export

Physical Review Letters, Vol. 92, No. 19. (May 2004), 195702.

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Concentrated suspensions of model colloidal hard spheres at a wall were studied in real space by means of time-resolved fluorescence confocal scanning microscopy. Both structure and dynamics of these systems differ dramatically from their bulk analogs (i.e.; far away from a wall). In particular; systems that are a glass in the bulk show significant hexagonal order at a wall. Upon increasing the volume fraction of the colloids; a reentrant melting transition involving a hexatic structure is observed. The last observation points to two-dimensional behavior of matter at walls.


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