The circular dichroism of helical chromophore aggregates as studied by a self-consistent non-linear response theory Export

@article{Kamiya1986, abstract = {An extended formulation of the circular dichroism of helical chromophore aggregates is given by means of the self-consistent non-linear response theory. In this formulation the helix circular dichroism is expressed in closed form in terms of the chromophore's polarizability and hyperpolarizability and in terms of the retarded helical-lattice sum of interchromophoric dipole-dipole interactions. The effects of interchromophoric dynamic interactions upon the helix circular dichroism are then absorbed self-consistently into the polarizability and hyperpolarizability band shape matrices of the perturbed chromophore. The utility of this formulation is shown by a sample calculation of the polarizability and first-hyperpolarizability contribution effects upon the circular dichroism band shape of an oriented helix modelling the B-form conformation of polynucleotides.}, author = {Kamiya, M.}, citeulike-article-id = {5718045}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/0301-0104(86)80011-8}, citeulike-linkout-1 = {http://linkinghub.elsevier.com/retrieve/pii/0301-0104(86)80011-8}, day = {1}, doi = {10.1016/0301-0104(86)80011-8}, issn = {03010104}, journal = {Chemical Physics}, keywords = {chirality, mathematics, self-assembly, spectroscopy}, month = {March}, number = {3}, pages = {395--405}, posted-at = {2009-09-03 14:20:00}, priority = {2}, title = {The circular dichroism of helical chromophore aggregates as studied by a self-consistent non-linear response theory}, url = {http://dx.doi.org/10.1016/0301-0104(86)80011-8}, volume = {102}, year = {1986} }

TY - JOUR ID - Kamiya1986 L3 - citeulike-article-id:5718045 N2 - An extended formulation of the circular dichroism of helical chromophore aggregates is given by means of the self-consistent non-linear response theory. In this formulation the helix circular dichroism is expressed in closed form in terms of the chromophore's polarizability and hyperpolarizability and in terms of the retarded helical-lattice sum of interchromophoric dipole-dipole interactions. The effects of interchromophoric dynamic interactions upon the helix circular dichroism are then absorbed self-consistently into the polarizability and hyperpolarizability band shape matrices of the perturbed chromophore. The utility of this formulation is shown by a sample calculation of the polarizability and first-hyperpolarizability contribution effects upon the circular dichroism band shape of an oriented helix modelling the B-form conformation of polynucleotides. IS - 3 JF - Chemical Physics SN - 03010104 EP - 405 TI - The circular dichroism of helical chromophore aggregates as studied by a self-consistent non-linear response theory VL - 102 SP - 395 KW - chirality KW - mathematics KW - self-assembly KW - spectroscopy AU - Kamiya, M PY - 1986/03/01/ UR - http://dx.doi.org/10.1016/0301-0104(86)80011-8 ER -