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Charge Ordering Induces a Smectic Phase in Oblate Ionic Liquid Crystals

by: G. C. Ganzenmüller, G. N. Patey
Physical Review Letters, Vol. 105 (Sep 2010), 137801, doi:10.1103/physrevlett.105.137801  Key: citeulike:11936154

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Abstract

We report a computer simulation study of an electroneutral mixture of oppositely charged oblate ellipsoids of revolution with aspect ratio A=1/3. In contrast with hard or soft repulsive ellipsoids, which are purely nematic, this system exhibits a smectic-A phase in which charges of equal sign are counterintuitively packed in layers perpendicular to the nematic director.


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