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Lifetime of the bond network and gel-like anomalies in supercooled water

by: Francesco Sciortino, Peter H. Poole, H. Eugene Stanley, Shlomo Havlin
Physical Review Letters, Vol. 64 (Apr 1990), pp. 1686-1689, doi:10.1103/physrevlett.64.1686  Key: citeulike:12103971

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Abstract

We analyze the distribution of bond lifetimes in simulations of liquid water using a novel bond definition. We find that the characteristic lifetimes of the bonds and of the ‘‘gel’’ network itself both increase strongly when temperature is decreased–and even appear to diverge at a temperature well below the freezing temperature–thereby providing an appealing physical picture of the anomalous behavior of water in the supercooled region.


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