Gas chromatographic retention of alkyl phosphates on ionic liquid stationary phases

Retention behaviors of alkyl phosophates were studied on a series of ionic liquid gas chromatography columns. The selectivity of the IL columns for alkyl phosphates were compared with a 5% phenyl column as a route to evaluating the potential use of IL columns in the analysis of alkyl phosphates in petroleum samples in both one- and multi-dimensional GC. Most interestingly, we demonstrate for the first time the dependence of elution order on separation temperature for members of a homologous series of compounds. At low temperatures it was found that trihexyl phosphate eluted before trioctyl phosphate, while at higher temperatures this pattern was reversed. ⺠Selectivity of IL columns for alkyl phosphates compared. ⺠Elution order changes with temperature for homologous series. ⺠Thermodynamic study shown as tool for column selection.