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Nonpolar, Polar, and Associating Solutes in Ionic Liquids

by: José N. Canongia Lopes, Margarida F. Costa Gomes, Agílio A. H. Pádua
J. Phys. Chem. B In The Journal of Physical Chemistry B, Vol. 110, No. 34. (1 August 2006), pp. 16816-16818, doi:10.1021/jp063603r  Key: citeulike:12036592

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Abstract

The existence of microphase segregation between polar and nonpolar domains in ionic liquids changes the way in which solvation can be understood in these media. Here, we perform a structural analysis on the solvation of nonpolar, polar, and associating solutes in imidazolium-based ionic liquids, where this novel way of understanding their nature as microsegregated solvents is correlated with their ability to interact with different species in diverse and complex ways.


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