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J. Am. Chem. Soc. In Journal of the American Chemical Society, Vol. 129, No. 2. (20 December 2006), pp. 284-285, doi:10.1021/ja067427b Key: citeulike:12060477
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Molar enthalpies of vaporization, of a homologous series of 1-alkyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imides, [Cnmim][NTf2], (with 2 ≤ n ≤ 8) were directly determined for the first time. The results obtained in this study emphasize and constitute clear experimental support for the novel concept that these liquid salts are composed of polar and nonpolar domains; that is, they exhibit microphase segregation. Molar enthalpies of vaporization, of a homologous series of 1-alkyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imides, [Cnmim][NTf2], (with 2 ≤ n ≤ 8) were directly determined for the first time. The results obtained in this study emphasize and constitute clear experimental support for the novel concept that these liquid salts are composed of polar and nonpolar domains; that is, they exhibit microphase segregation.
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