Solubility of Alcohols and Aromatic Compounds in Imidazolium-Based Ionic Liquids

@article{citeulike:3459746, abstract = {Abstract: Liquidliquid equilibria for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) or 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) + 1-propanol, + 1-butanol, and + 1-pentanol in the temperature range of (293.92 to 364.88) K and the solubility of benzene, toluene, and thiophene in [BMIM][PF6] and [BMIM][BF4] in the temperature range of (298.15 to 343.15) K have been measured using the cloud point method. The liquidliquid equilibrium data were correlated by the nonrandom two-liquid (NRTL) equation, and the root-mean-square deviations of the mole fractions for [BMIM][PF6] or [BMIM][BF4] + 1-propanol, 1-butanol, and 1-pentanol are shown as follow: 0.0041, 0.0065, 0.0043, 0.0065, 0.0053, and 0.0019, respectively. In addition, it is found that the solubility of benzene, toluene, and thiophene in the ionic liquids was independent of temperature.}, address = {Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, Peoples Republic of China}, author = {Huo, Yan and Xia, Shuqian and Ma, Peisheng}, citeulike-article-id = {3459746}, doi = {10.1021/je800331n}, journal = {J. Chem. Eng. Data}, keywords = {alcohols, aromatic, ionic, liquid, lle, rtil, solubility}, month = {October}, posted-at = {2008-10-29 10:02:34}, priority = {0}, title = {Solubility of Alcohols and Aromatic Compounds in Imidazolium-Based Ionic Liquids}, url = {http://dx.doi.org/10.1021/je800331n}, year = {2008} }

TY - JOUR ID - citeulike:3459746 L3 - citeulike-article-id:3459746 N2 - Abstract: Liquidliquid equilibria for 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) or 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) + 1-propanol, + 1-butanol, and + 1-pentanol in the temperature range of (293.92 to 364.88) K and the solubility of benzene, toluene, and thiophene in [BMIM][PF6] and [BMIM][BF4] in the temperature range of (298.15 to 343.15) K have been measured using the cloud point method. The liquidliquid equilibrium data were correlated by the nonrandom two-liquid (NRTL) equation, and the root-mean-square deviations of the mole fractions for [BMIM][PF6] or [BMIM][BF4] + 1-propanol, 1-butanol, and 1-pentanol are shown as follow: 0.0041, 0.0065, 0.0043, 0.0065, 0.0053, and 0.0019, respectively. In addition, it is found that the solubility of benzene, toluene, and thiophene in the ionic liquids was independent of temperature. JF - J. Chem. Eng. Data AD - Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, Peoples Republic of China TI - Solubility of Alcohols and Aromatic Compounds in Imidazolium-Based Ionic Liquids KW - alcohols KW - aromatic KW - ionic KW - liquid KW - lle KW - rtil KW - solubility AU - Huo, Yan AU - Xia, Shuqian AU - Ma, Peisheng PY - 2008/10/22/ UR - http://dx.doi.org/10.1021/je800331n ER -