Novel inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Binary mixtures of alkali bis(fluorosulfonyl)amides Export

@article{citeulike:3767118, abstract = {Thermal properties of alkali bis(fluorosulfonyl)amides, MFSI (M = Li, Na, K, Rb, Cs), have been investigated. Binary phase diagrams of LiFSI-KFSI and NaFSI-KFSI systems have been constructed. Eutectic point for LiFSI-KFSI is 338 K at (xLi, xK) = (0.45, 0.55) and, that for NaFSI-KFSI is 330 K at (xNa, xK) = (0.45, 0.55). The electrochemical window of the eutectic LiFSI-KFSI is as wide as 6.0 V at 348 K with the cathode limit being lithium metal deposition. The electrochemical window of the eutectic NaFSI-KFSI is 5.0 V at 340 K with sodium metal deposition at the cathode limit. These new inorganic ionic liquids are highly promising for various electrochemical applications. {\copyright} 2008 Elsevier B.V. All rights reserved.}, address = {Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan}, author = {Kubota, K. and Nohira, T. and Goto, T. and Hagiwara, R.}, citeulike-article-id = {3767118}, citeulike-linkout-0 = {http://www.scopus.com/scopus/inward/record.url?eid=2-s2.0-56249137234&partnerID=40}, comment = {Source: Scopus ---=note-separator=--- Export Date: 10 December 2008}, journal = {Electrochemistry Communications}, keywords = {battery, bisfluorosulfonylamide, electrodeposition, electrolytes, fsi, ionic, liquid, liquids, lithium, rtil, sodium}, number = {12}, pages = {1886--1888}, posted-at = {2008-12-10 10:01:47}, priority = {2}, title = {Novel inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Binary mixtures of alkali bis(fluorosulfonyl)amides}, url = {http://www.scopus.com/scopus/inward/record.url?eid=2-s2.0-56249137234&partnerID=40}, volume = {10}, year = {2008} }

TY - JOUR ID - citeulike:3767118 L3 - citeulike-article-id:3767118 N2 - Thermal properties of alkali bis(fluorosulfonyl)amides, MFSI (M = Li, Na, K, Rb, Cs), have been investigated. Binary phase diagrams of LiFSI-KFSI and NaFSI-KFSI systems have been constructed. Eutectic point for LiFSI-KFSI is 338 K at (xLi, xK) = (0.45, 0.55) and, that for NaFSI-KFSI is 330 K at (xNa, xK) = (0.45, 0.55). The electrochemical window of the eutectic LiFSI-KFSI is as wide as 6.0 V at 348 K with the cathode limit being lithium metal deposition. The electrochemical window of the eutectic NaFSI-KFSI is 5.0 V at 340 K with sodium metal deposition at the cathode limit. These new inorganic ionic liquids are highly promising for various electrochemical applications. © 2008 Elsevier B.V. All rights reserved. IS - 12 JF - Electrochemistry Communications AD - Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan EP - 1888 TI - Novel inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Binary mixtures of alkali bis(fluorosulfonyl)amides VL - 10 SP - 1886 KW - battery KW - bisfluorosulfonylamide KW - electrodeposition KW - electrolytes KW - fsi KW - ionic KW - liquid KW - liquids KW - lithium KW - rtil KW - sodium N1 - Source: Scopus N1 - Export Date: 10 December 2008 AU - Kubota, K AU - Nohira, T AU - Goto, T AU - Hagiwara, R PY - 2008/// UR - http://www.scopus.com/scopus/inward/record.url?eid=2-s2.0-56249137234&partnerID=40 ER -