Alkylammonium-Based Protic Ionic Liquids. II. Ionic Transport and Heat-Transfer Properties: Fragility and Ionicity Rule Export

@article{citeulike:4374059, abstract = {The physicochemical characterization of six alkylammonium-based protic ionic liquids (PILs) is presented. These compounds were prepared through a simple and atom-economic neutralization reaction between a tertiary amine and a Br{\o}nsted acid, HX, where X− is HCOO−, CH3COO−, HF2−. The temperature dependency and the effect of added water on properties such as density, viscosity, ionic conductivity, and the thermal comportment of these PILs were measured and investigated. The results allowed us to classify them according to a classical Walden diagram and to appreciate their great ” fragility”. PILs have applicable perspectives in replacements of conventional inorganic acids for fuel cell devices and thermal transfer fluids.}, author = {Anouti, M\'{e}ri\`{e}m and Caillon-Caravanier, Magaly and Le Floch, Corinne and Lemordant, Daniel}, citeulike-article-id = {4374059}, citeulike-linkout-0 = {http://dx.doi.org/10.1021/jp803489n}, citeulike-linkout-1 = {http://pubs.acs.org/doi/abs/10.1021/jp803489n}, day = {1}, doi = {10.1021/jp803489n}, journal = {The Journal of Physical Chemistry B}, keywords = {alkylammonium, properties, rtil}, month = {August}, number = {31}, pages = {9412--9416}, posted-at = {2009-04-22 10:17:40}, priority = {2}, title = {Alkylammonium-Based Protic Ionic Liquids. II. Ionic Transport and Heat-Transfer Properties: Fragility and Ionicity Rule}, url = {http://dx.doi.org/10.1021/jp803489n}, volume = {112}, year = {2008} }

TY - JOUR ID - citeulike:4374059 L3 - citeulike-article-id:4374059 N2 - The physicochemical characterization of six alkylammonium-based protic ionic liquids (PILs) is presented. These compounds were prepared through a simple and atom-economic neutralization reaction between a tertiary amine and a Brønsted acid, HX, where X− is HCOO−, CH3COO−, HF2−. The temperature dependency and the effect of added water on properties such as density, viscosity, ionic conductivity, and the thermal comportment of these PILs were measured and investigated. The results allowed us to classify them according to a classical Walden diagram and to appreciate their great “fragility”. PILs have applicable perspectives in replacements of conventional inorganic acids for fuel cell devices and thermal transfer fluids. IS - 31 JF - The Journal of Physical Chemistry B EP - 9416 TI - Alkylammonium-Based Protic Ionic Liquids. II. Ionic Transport and Heat-Transfer Properties: Fragility and Ionicity Rule VL - 112 SP - 9412 KW - alkylammonium KW - properties KW - rtil AU - Anouti, Mérièm AU - Caillon-Caravanier, Magaly AU - Le Floch, Corinne AU - Lemordant, Daniel PY - 2008/08/01/ UR - http://dx.doi.org/10.1021/jp803489n ER -