Bridging the Gap between Ionic Liquids and Molten Salts: Group 1 Metal Salts of the Bistriflamide Anion in the Gas Phase Export

@article{citeulike:4730816, abstract = {Fourier transform ion cyclotron resonance mass spectrometry experiments showed that liquid Group 1 metal salts of the bistriflamide anion undergoing reduced-pressure distillation exhibit a remarkable behavior that is in transition between that of the vapor−liquid equilibrium characteristics of aprotic ionic liquids and that of the Group 1 metal halides: the unperturbed vapors resemble those of aprotic ionic liquids, in the sense that they are essentially composed of discrete ion pairs. However, the formation of large aggregates through a succession of ion−molecule reactions is closer to what might be expected for Group 1 metal halides. Similar experiments were also carried out with bis{(trifluoromethyl)sulfonyl}amine to investigate the effect of H+, which despite being the smallest Group 1 cation, is generally regarded as a nonmetal species. In this case, instead of the complex ion−molecule reaction pattern found for the vapors of Group 1 metal salts, an equilibrium similar to those observed for aprotic ionic liquids was observed.}, author = {Leal, João P. and da Piedade, Manuel E. and Canongia and Tomaszowska, Alina A. and Esperança, José M. and Rebelo, Luís P. and Seddon, Kenneth R.}, citeulike-article-id = {4730816}, citeulike-linkout-0 = {http://dx.doi.org/10.1021/jp811039b}, citeulike-linkout-1 = {http://pubs.acs.org/doi/abs/10.1021/jp811039b}, comment = {Velmi zaj\'{\i}mav\'{y} \v{c}l\'{a}nek, sublimace sol\'{\i} a IL, tvorba agreg\'{a}t\r{u} v parn\'{\i} f\'{a}zi. Pou\v{z}it\'{\i} Kugelrohrova apar\'{a}tu na su\v{s}en\'{\i}.}, day = {19}, doi = {10.1021/jp811039b}, journal = {The Journal of Physical Chemistry B}, keywords = {aprotic, fourier, halide, mass\_spectrometry, rtil, vle}, month = {March}, number = {11}, pages = {3491--3498}, posted-at = {2009-06-03 10:11:28}, priority = {0}, title = {Bridging the Gap between Ionic Liquids and Molten Salts: Group 1 Metal Salts of the Bistriflamide Anion in the Gas Phase}, url = {http://dx.doi.org/10.1021/jp811039b}, volume = {113}, year = {2009} }

TY - JOUR ID - citeulike:4730816 L3 - citeulike-article-id:4730816 N2 - Fourier transform ion cyclotron resonance mass spectrometry experiments showed that liquid Group 1 metal salts of the bistriflamide anion undergoing reduced-pressure distillation exhibit a remarkable behavior that is in transition between that of the vapor−liquid equilibrium characteristics of aprotic ionic liquids and that of the Group 1 metal halides: the unperturbed vapors resemble those of aprotic ionic liquids, in the sense that they are essentially composed of discrete ion pairs. However, the formation of large aggregates through a succession of ion−molecule reactions is closer to what might be expected for Group 1 metal halides. Similar experiments were also carried out with bis{(trifluoromethyl)sulfonyl}amine to investigate the effect of H+, which despite being the smallest Group 1 cation, is generally regarded as a nonmetal species. In this case, instead of the complex ion−molecule reaction pattern found for the vapors of Group 1 metal salts, an equilibrium similar to those observed for aprotic ionic liquids was observed. IS - 11 JF - The Journal of Physical Chemistry B EP - 3498 TI - Bridging the Gap between Ionic Liquids and Molten Salts: Group 1 Metal Salts of the Bistriflamide Anion in the Gas Phase VL - 113 SP - 3491 KW - aprotic KW - fourier KW - halide KW - mass_spectrometry KW - rtil KW - vle N1 - Velmi zajímavý článek, sublimace solí a IL, tvorba agregátů v parní fázi. Použití Kugelrohrova aparátu na sušení. AU - Leal, João AU - da Piedade, Manuel AU - Canongia AU - Tomaszowska, Alina AU - Esperança, José AU - Rebelo, Luís AU - Seddon, Kenneth PY - 2009/03/19/ UR - http://dx.doi.org/10.1021/jp811039b ER -