Solubility of CO2 in dialkylimidazolium dialkylphosphate ionic liquids Export

@article{citeulike:5026125, abstract = {The solubility of carbon dioxide in room temperature ionic liquids (RTILs), dialkylimidazolium dialkylphosphates, was measured at 313–333 K and at pressures close to atmospheric pressure, from which Henry's law coefficients, standard Gibbs free energy, enthalpy, and entropy changes of solvation were derived. The CO 2 solubility in the dialkylimidazolium dialkylphosphate was found to increase with increasing chain length of the alkyl groups on the cation and/or the anion as was similarly found in other RTILs. Among various dialkylimidazolium dialkylphosphates tested, 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM][Et 2 PO 4 ]) and 1-butyl-3-methylimidazolium dibutylphosphate ([BMIM][Bu 2 PO 4 ]) exhibited the comparable or better capability of dissolving CO 2 in comparison with that of [BMIM][BF 4 ], but their absorption capacities were still lower than that of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM][Tf 2 N]).}, author = {Palgunadi, Jelliarko and Kang, Je E. and Nguyen, Dinh Q. and Kim, Jin H. and Min, Byoung K. and Lee, Sang D. and Kim, Honggon and Kim, Hoon S.}, citeulike-article-id = {5026125}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/j.tca.2009.04.022}, citeulike-linkout-1 = {http://linkinghub.elsevier.com/retrieve/pii/S004060310900210X}, day = {05}, doi = {10.1016/j.tca.2009.04.022}, issn = {00406031}, journal = {Thermochimica Acta}, keywords = {carbondioxide, rtil, solubility}, month = {May}, posted-at = {2009-09-18 10:53:30}, priority = {2}, title = {Solubility of CO2 in dialkylimidazolium dialkylphosphate ionic liquids}, url = {http://dx.doi.org/10.1016/j.tca.2009.04.022}, year = {2009} }

TY - JOUR ID - citeulike:5026125 L3 - citeulike-article-id:5026125 N2 - The solubility of carbon dioxide in room temperature ionic liquids (RTILs), dialkylimidazolium dialkylphosphates, was measured at 313–333 K and at pressures close to atmospheric pressure, from which Henry's law coefficients, standard Gibbs free energy, enthalpy, and entropy changes of solvation were derived. The CO 2 solubility in the dialkylimidazolium dialkylphosphate was found to increase with increasing chain length of the alkyl groups on the cation and/or the anion as was similarly found in other RTILs. Among various dialkylimidazolium dialkylphosphates tested, 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM][Et 2 PO 4 ]) and 1-butyl-3-methylimidazolium dibutylphosphate ([BMIM][Bu 2 PO 4 ]) exhibited the comparable or better capability of dissolving CO 2 in comparison with that of [BMIM][BF 4 ], but their absorption capacities were still lower than that of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM][Tf 2 N]). JF - Thermochimica Acta SN - 00406031 TI - Solubility of CO2 in dialkylimidazolium dialkylphosphate ionic liquids KW - carbondioxide KW - rtil KW - solubility AU - Palgunadi, Jelliarko AU - Kang, Je AU - Nguyen, Dinh AU - Kim, Jin AU - Min, Byoung AU - Lee, Sang AU - Kim, Honggon AU - Kim, Hoon PY - 2009/05/05/ UR - http://dx.doi.org/10.1016/j.tca.2009.04.022 ER -