(Liquid+liquid) equilibria in the binary systems (aliphatic, or aromatic hydrocarbons+1-ethyl-3-methylimidazolium ethylsulfate, or 1-butyl-3-methylimidazolium methylsulfate ionic liquids) Export

@article{citeulike:5444407, abstract = {(Liquid + liquid) equilibria of 14 binary systems composed of n -hexane, n -heptane, benzene, toluene, o -xylene, m -xylene, or p -xylene and 1-ethyl-3-methylimidazolium ethylsulfate, [emim]EtSO 4 , or 1-butyl-3-methylimidazolium methylsulfate, [bmim]MeSO 4 , ionic liquids have been done in the temperature range from (293.2 to 333.2) K. The solubility of aliphatic is less than those of the aromatic hydrocarbons. In particular, the solubility of hydrocarbons in both ionic liquids increases with the temperature in the order n -heptane <  n -hexane <  m -xylene <  p -xylene <  o -xylene < toluene < benzene. Considering the high solubility of aromatics and the low solubility of aliphatic hydrocarbons as well as totally immiscibility of the ionic liquids in all hydrocarbons, these new green solvents may be used as potentials extracting solvents for the separation of aromatic and aliphatic hydrocarbons.}, author = {Garc\'{\i}a, Juli\'{a}n and Torrecilla, Jos\'{e} S. and Fern\'{a}ndez, Adela and Oliet, Mercedes and Rodr\'{\i}guez, Francisco}, citeulike-article-id = {5444407}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/j.jct.2009.07.023}, citeulike-linkout-1 = {http://linkinghub.elsevier.com/retrieve/pii/S0021961409001979}, comment = {Dobr\'{y} \v{c}l\'{a}nek o m\v{e}\v{r}en\'{\i} rozpustnost\'{\i}, bere v \'{u}vahu i velk\'{e} mezif\'{a}zov\'{e} nap\v{e}t\'{\i} mezi IL a uhlovod\'{\i}kovou f\'{a}z\'{\i}.}, day = {06}, doi = {10.1016/j.jct.2009.07.023}, issn = {00219614}, journal = {The Journal of Chemical Thermodynamics}, keywords = {binary, emimethylsulfate, hydrocarbon, lle, rtil}, month = {January}, number = {1}, pages = {144--150}, posted-at = {2009-10-12 12:36:40}, priority = {0}, title = {(Liquid+liquid) equilibria in the binary systems (aliphatic, or aromatic hydrocarbons+1-ethyl-3-methylimidazolium ethylsulfate, or 1-butyl-3-methylimidazolium methylsulfate ionic liquids)}, url = {http://dx.doi.org/10.1016/j.jct.2009.07.023}, volume = {42}, year = {2010} }

TY - JOUR ID - citeulike:5444407 L3 - citeulike-article-id:5444407 N2 - (Liquid + liquid) equilibria of 14 binary systems composed of n -hexane, n -heptane, benzene, toluene, o -xylene, m -xylene, or p -xylene and 1-ethyl-3-methylimidazolium ethylsulfate, [emim]EtSO 4 , or 1-butyl-3-methylimidazolium methylsulfate, [bmim]MeSO 4 , ionic liquids have been done in the temperature range from (293.2 to 333.2) K. The solubility of aliphatic is less than those of the aromatic hydrocarbons. In particular, the solubility of hydrocarbons in both ionic liquids increases with the temperature in the order n -heptane <  n -hexane <  m -xylene <  p -xylene <  o -xylene < toluene < benzene. Considering the high solubility of aromatics and the low solubility of aliphatic hydrocarbons as well as totally immiscibility of the ionic liquids in all hydrocarbons, these new green solvents may be used as potentials extracting solvents for the separation of aromatic and aliphatic hydrocarbons. IS - 1 JF - The Journal of Chemical Thermodynamics SN - 00219614 EP - 150 TI - (Liquid+liquid) equilibria in the binary systems (aliphatic, or aromatic hydrocarbons+1-ethyl-3-methylimidazolium ethylsulfate, or 1-butyl-3-methylimidazolium methylsulfate ionic liquids) VL - 42 SP - 144 KW - binary KW - emimethylsulfate KW - hydrocarbon KW - lle KW - rtil N1 - Dobrý článek o měření rozpustností, bere v úvahu i velké mezifázové napětí mezi IL a uhlovodíkovou fází. AU - García, Julián AU - Torrecilla, José AU - Fernández, Adela AU - Oliet, Mercedes AU - Rodríguez, Francisco PY - 2010/01/06/ UR - http://dx.doi.org/10.1016/j.jct.2009.07.023 ER -