Reversible addition-fragmentation chain-transfer polymerization: Unambiguous end-group assignment via electrospray ionization mass spectrometry Export

@article{citeulike:6095751, abstract = {Electrospray ionization mass spectrometry was performed to identify the structure of polymeric methyl acrylates generated via the cumyl dithiobenzoate (CDB), cumyl p-fluorodithiobenzoate (CPFDB), and 1-phenylethyl dithiobenzoate (PEDB) mediated reversible addition-fragmentation chain-transfer (RAFT) polymerizations. The relatively simple spectra clearly demonstrate the end groups of this living free-radical polymerization technique. Only polymeric chains carrying one leaving group of the RAFT agent and the dithiobenzoate end group as the active RAFT center were discovered. Multiple-stage mass spectrometric experiments and oxidation of the dithioester end group confirmed the structure of the generated polymers. {\copyright} 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4032-4037, 2002}, address = {Centre for Advanced Macromolecular Design, School of Chemical Engineering and Industrial Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia}, author = {Vana, Philipp and Albertin, Luca and Barner, Leonie and Davis, Thomas P. and Barner-Kowollik, Christopher}, citeulike-article-id = {6095751}, citeulike-linkout-0 = {http://dx.doi.org/10.1002/pola.10500}, citeulike-linkout-1 = {http://www3.interscience.wiley.com/cgi-bin/abstract/99016110/ABSTRACT}, doi = {10.1002/pola.10500}, issn = {1099-0518}, journal = {Journal of Polymer Science Part A: Polymer Chemistry}, keywords = {091110}, number = {22}, pages = {4032--4037}, posted-at = {2009-11-10 20:10:34}, priority = {2}, title = {Reversible addition-fragmentation chain-transfer polymerization: Unambiguous end-group assignment via electrospray ionization mass spectrometry}, url = {http://dx.doi.org/10.1002/pola.10500}, volume = {40}, year = {2002} }

TY - JOUR ID - citeulike:6095751 L3 - citeulike-article-id:6095751 N2 - Electrospray ionization mass spectrometry was performed to identify the structure of polymeric methyl acrylates generated via the cumyl dithiobenzoate (CDB), cumyl p-fluorodithiobenzoate (CPFDB), and 1-phenylethyl dithiobenzoate (PEDB) mediated reversible addition-fragmentation chain-transfer (RAFT) polymerizations. The relatively simple spectra clearly demonstrate the end groups of this living free-radical polymerization technique. Only polymeric chains carrying one leaving group of the RAFT agent and the dithiobenzoate end group as the active RAFT center were discovered. Multiple-stage mass spectrometric experiments and oxidation of the dithioester end group confirmed the structure of the generated polymers. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4032-4037, 2002 IS - 22 JF - Journal of Polymer Science Part A: Polymer Chemistry SN - 1099-0518 AD - Centre for Advanced Macromolecular Design, School of Chemical Engineering and Industrial Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia EP - 4037 TI - Reversible addition-fragmentation chain-transfer polymerization: Unambiguous end-group assignment via electrospray ionization mass spectrometry VL - 40 SP - 4032 KW - 091110 AU - Vana, Philipp AU - Albertin, Luca AU - Barner, Leonie AU - Davis, Thomas AU - Barner-Kowollik, Christopher PY - 2002/// UR - http://dx.doi.org/10.1002/pola.10500 ER -