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J. Am. Chem. Soc. In Journal of the American Chemical Society, Vol. 132, No. 44. (14 October 2010), pp. 15814-15819, doi:10.1021/ja1076662 Key: citeulike:11868125
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Pyridine-functionalized single-walled carbon nanotubes (SWNTs) are prepared from the addition of a pyridine diazonium salt to nanotubes. The location and distribution of the functional groups is determined by atomic force microscopy using electrostatic interactions with gold nanoparticles. The pyridine-functionalized SWNTs are able to act as cross-linkers and hydrogen bond to poly(acrylic acid) to form SWNT hydrogels. The pyridine-functionalized SWNTs are further characterized using Raman, FTIR, UV/vis?NIR, and X-ray photoelectron spectroscopy and thermogravimetric analysis?mass spectrometry.
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