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Pulling polymers adsorbed on a striped surface

by: G. K. Iliev, E. Orlandini, S. G. Whittington
Journal of Physics A: Mathematical and Theoretical, Vol. 46, No. 5. (17 January 2013), 055001, doi:10.1088/1751-8113/46/5/055001  Key: citeulike:11922713

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Abstract

We consider the adsorption of a linear homopolymer on a striped surface where the monomers have different energies of interaction with each of the two kinds of stripe. In addition, the polymer is subject to a force that tends to desorb the polymer, and the force can be applied at different angles. We consider both a partially directed walk model and a self-avoiding walk model. We solve the problem for the partially directed walk problem essentially completely and give phase diagrams (in the force-temperature plane) for various values of the direction in which the force is applied. The phase diagrams show re-entrance phenomena and, for some force directions, degenerate ground states. We also present a low temperature treatment that helps to interpret the results from the combinatorial solution. For the self-avoiding walk model we present Monte Carlo results and show that the phase diagrams for the partially directed walk and self-avoiding walk are qualitatively similar and, at low temperatures, are in quantitative agreement.


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