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Elasticity of agr-Cristobalite: A Silicon Dioxide with a Negative Poisson's Ratio Export

Science, Vol. 257, No. 5070. (31 July 1992), pp. 650-652.

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cristobalite poisson

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Laser Brillouin spectroscopy was used to determine the adiabatic single-crystal elastic stiffness coefficients of silicon dioxide (SiO2) in the [agr]-cristobalite structure. This SiO2 polymorph, unlike other silicas and silicates, exhibits a negative Poisson's ratio; [agr]-cristobalite contracts laterally when compressed and expands laterally when stretched. Tensorial analysis of the elastic coefficients shows that Poisson's ratio reaches a maximum value of -0.5 in some directions, whereas averaged values for the single-phased aggregate yield a Poisson's ratio of -0.16. 10.1126/science.257.5070.650


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