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Ferruginous Conditions Dominated Later Neoproterozoic Deep-Water Chemistry Export

Science, Vol. 321, No. 5891. (15 August 2008), pp. 949-952.

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anoxia chemistry climate deep-water iron neoproterozoic ocean paleoclimate proterozoic

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Earth's surface chemical environment has evolved from an early anoxic condition to the oxic state we have today. Transitional between an earlier Proterozoic world with widespread deep-water anoxia and a Phanerozoic world with large oxygen-utilizing animals, the Neoproterozoic Era [1000 to 542 million years ago (Ma)] plays a key role in this history. The details of Neoproterozoic Earth surface oxygenation, however, remain unclear. We report that through much of the later Neoproterozoic (<742 +/- 6 Ma), anoxia remained widespread beneath the mixed layer of the oceans; deeper water masses were sometimes sulfidic but were mainly Fe2+-enriched. These ferruginous conditions marked a return to ocean chemistry not seen for more than one billion years of Earth history. 10.1126/science.1154499


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